If you imply links between the molecules of
polymers, but not component parts of these molecules, forces of bonds between
them are Van-der-Vaal's forces( without the transmission of electrons from atoms ),
i.e. intermolecular. Polymerization of molecules looks, as growth of loops on the
surface layer of catalyst- one molecule grows from an active center, and then a
free end is adsorbed by the surface of catalyst and fastened ( it looks as
knitting of lace)) On other end of molecule a monomer initiate the growth of
loop.By formation of row of such loops a primary lamel is formed,the separate
loops of which are connected by intermolecular forces .A primary lamel is a basis
for crystallization of new areas of growing chain. This chart works at the
design of fibrils or other anisometric matters too. The weakness of these
connections is deceitful, because at sufficient length of filaments sum of
energies of these links is more than sum of energies of links which filaments are
built from . Therefore even such loosely-coupled links are rarely broken by the
fluctuations of thermal energy.
Tuesday, September 30, 2014
Are cross links (in terms of bonds between polymers) an example of intermolecular bonds?
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